That 5 pin DIN output is not balanced.
Pin 2 is Common/Ground.
Pins 1 and 3 are shorted together, and are the signal for the Pianet.
Pins 4 and 5 are shorted together, and are the signal for the Clav.
If you send the Duo's DIN 1 and 3 (or 4 and 5) to an XLR's + and - (pins 2 and 3), and Duo DIN 2 to XLR pin 1, a true XLR balanced input will subtract pin 3 from 2, hence the signal from itself, and you will end up with nothing.
So other than convenience or compatibility with older European stereo equipment,
the 5 pin DIN is no better than 2 separate 1/4" unbalanced instrument cables hooked to the separate Pianet and Clavinet outputs.
Pin 2 is Common/Ground.
Pins 1 and 3 are shorted together, and are the signal for the Pianet.
Pins 4 and 5 are shorted together, and are the signal for the Clav.
If you send the Duo's DIN 1 and 3 (or 4 and 5) to an XLR's + and - (pins 2 and 3), and Duo DIN 2 to XLR pin 1, a true XLR balanced input will subtract pin 3 from 2, hence the signal from itself, and you will end up with nothing.
So other than convenience or compatibility with older European stereo equipment,
the 5 pin DIN is no better than 2 separate 1/4" unbalanced instrument cables hooked to the separate Pianet and Clavinet outputs.